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Bücher Englische Bücher Wissen & Bildung Naturwissenschaft, Medizin, Informatik, Technik Chemie Organische Chemie Synthetic Organic Sonochemistry
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Synthetic Organic Sonochemistry
Jean-Louis Luche (Taschenbuch, Englisch)
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Beschreibung
TEAN-LOUIS LUCHE A French poet of this eentury, Pierre Mae Orlan, wrote "Adventure does not exist, it is only in the mind of he who is pursuing it, and, as soon as it is at one's finger tips, it vanishes to come back to life, far away, in a different shape, at the frontiers of imagination". This sentence could be used to define the adventure that many sonochemists experienced. Most of them did not… even suspect that the "laboratory trick" they were using was the first contact with a considerable amount of science. If a personal note is allowed here, it ean be interesting to mention the part played by chance in my involvement in sonochemistry. Almost 20 years ago, we had to perform an apparently simple Grignard reaetion with n-butylmagnesium bromide and geranial, but the results were repeatedly unsatisfactory. The one-pot Barbier technique was attempted, also without success. From my studies at the University, I imagined that the failure of the latter reaction could be caused by a common phenomenon known by solid state chemists as passivation, which in some cases can be overcome by ultrasonication. By chance, an ultrasonie bath was sitting on the next beneh, borrowed to clean some equipment. We clamped our reluctant reaction mixture into the bath, the reaction proceeded vigorously, and ... the adventure started. Without knowing anything about cavitation, high energies, ete., we had an illustration of Goethe's word "Am Anfang war die Tat" (at the Beginning was the Act). Dieses Produkt haben wir gerade leider nicht auf Lager.
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Technische Daten
Erscheinungsdatum
16.06.2013
Sprache
Englisch
EAN
9781489919120, 9781489919120
Herausgeber
Springer US
Sonderedition
Nein
Autor
Jean-Louis Luche
Seitenanzahl
431
Auflage
1
Einbandart
Taschenbuch
Schlagwörter
Cycloaddition, acoustics, electrochemistry, metals, organic synthesis, synthesis, ultrasound
Thema-Inhalt
PNN - Organische Chemie
PNR - Physikalische Chemie
PHDS - Wellenmechanik (Vibration und Akustik)
Höhe
235 mm
Breite
15.5 cm
Hersteller: Springer Nature Customer Service Center GmbH, Europaplatz 3, Heidelberg, Deutschland, 69115, ProductSafety@springernature.com
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★★★★★
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