Organic Synthesis with Palladium Compounds

01.02.1980

Englisch

9783540097679, 9783540097679

Springer Berlin

Reactivity and Structure: Concepts in Organic Chemistry

Nein

Jiro Tsuji

210

Gebundene Ausgabe

10

Synthese, Katalysator, Rearrangement reaction, Palladium, Rearrangement, Palladiumverbindung, Coupling reaction

PNN - Organische Chemie

I. Introduction.- II. Palladium Compounds and Complexes Useful in Organic Synthesis.- III. Oxidation Reactions with Pd2+ Compounds.- 1. Introduction.- 2. Reactions of Olefins.- a. Introduction.- b. Reactions of Water (Wacker Reaction).- c. Reactions of Alcohols, Phenols and Other Hydroxy Compounds.- d. Reactions of Carboxylic Acids.- e. Oxidative Carbonylation Reactions.- f. Reactions of Aromatic Compounds.- g. Reactions of Carbanions.- h. Reactions of Amines.- i. Reactions of Hydrogen Cyanide and Chloride.- j. Oxidative Coupling Reactions.- k. Reactions of Alkynes.- 3. Synthetic Reactions with ?-Allyl Complexes.- a. Introduction.- b. Methods of Preparing ?-Allylpalladium Complexes.- c. Reactions of Carbon Monoxide and Isocyanides.- d. Reactions of Active Methylene Compounds.- e. Reactions of Other Nucleophiles.- 4. Reactions of Aromatic Compounds.- 5. Synthetic Reactions by Transmetallation of Organomercury Compounds and Related Reactions.- 6. Synthetic Reactions Based on Chelation of Heteroatoms.- a. Ortho-Palladation of Aromatic Compounds.- b. Reactions of Allylic and Homoallylic Amines and Sulfides.- 7. Dehydrogenation Reactions.- 8. Reactions of Alkynes.- 9. Reactions of Alcohols and Carbon Monoxide.- 10. Miscellaneous Reactions.- IV. Catalytic Reactions.- 1. Introduction.- 2. Reactions of Olefins.- a. Carbonylation Reactions.- b. Addition Reactions (Oligomerization and Co-Oligomerization).- c. Hydrosilylation Reactions.- d. Miscellaneous Reactions.- 3. Reactions of Conjugated Dienes.- a. Introduction.- b. Oligomerization.- c. Telomerization with Water, Alcohols and Phenols.- d. Telomerization with Carboxylic Acids.- e. Telomerization with Ammonia and Amines.- f. Telomerization with Enamines.- g. Telomerization with Active Methylene and Methyne Compounds.- h. Reactions of Silicon Compounds.- i. Carbonylation Reactions.- j. Reactions of Phenylhydrazones and Oximes.- k. Cocyclization Reactions.- 1. Reactions of Carbon Dioxide.- m. Application of Butadiene Telomers to Natural Product Syntheses.- n. Dimerization and Telomerization of Isoprene and Other Dienes.- 4. Reactions of Allene.- 5. Reactions of Allyl Ethers, Esters, and Alcohols.- 6. Reactions of Alkenyl Ethers and Esters.- 7. Reactions of Organic Halides.- a. Allylic Halides.- b. Aryl Halides.- c. Alkenyl Halides.- d. Acyl Halides.- e. Reactions of ?-Halo Ketones and Benzyl Halides.- 8. Decarbonylation of Aldehydes.- 9. Reaction of Alkynes.- a. Carbonylation Reactions.- b. Addition and Cyclization Reactions.- c. Reactions with Silicon Compounds.- d. Miscellaneous Reaction.- 10. Reactions of Silicon Compounds.- 11. Reactions of Amines.- 12. Reactions of Isocyanides.- 13. Palladium Catalyzed Decomposition of Azo Compounds, Azides and Peroxides.- 14. Rearrangement Reactions Promoted by PdC12.- 15. Miscellaneous Reactions of Carbon Monoxide and Carbon Dioxide.- 16. Reductions.- 17. Miscellaneous Reactions.- References.

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