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Bücher Englische Bücher Wissen & Bildung Naturwissenschaft, Medizin, Informatik, Technik Chemie Organische Chemie Steric and Stereoelectronic Effects in Organic Chemistry
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Steric and Stereoelectronic Effects in Organic Chemistry
Veejendra K. Yadav (Gebundene Ausgabe, Englisch)
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Beschreibung
The steric and stereoelectronic effects control the rate and stereochemical outcome of reactions. Hence, a decent understanding of the related concepts is essential for successful synthetic planning. The book attempts to address several important issues related to these concepts in a simplified manner, and is intended for graduate students. It lays stress on the important aspects of steric and… stereoelectronic effects and their control on the conformational profile and reactivity features. The book covers the geometrical requirements for reactions at saturated and unsaturated carbons in both cyclic and acyclic systems, and the resultant stereochemical features. The aspect of geometrical flexibility is also covered with a few examples involving intramolecular reactions. It deals with the facial selectivity of nucleophilic additions to acyclic and cyclic carbonyl compounds, and explains how the steric and stereoelectronic effects control the same. The work comments on allylic strains and their stereochemical control on different reactions with the related conformational control. It is a must read to understand the control elements, the prominent among these elements are spiro-conjugation, periselectivity, torquoselectivity, a-effect, Hammett’s substituent constants, Hammond postulate, and Curtin-Hammett principle. Dieses Produkt haben wir gerade leider nicht auf Lager.
Handgeprüfte Gebrauchtware
Bis zu 50 % günstiger als neu
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Technische Daten
Erscheinungsdatum
16.06.2016
Sprache
Englisch
EAN
9789811011382, 9789811011382
Herausgeber
Springer Singapore
Sonderedition
Nein
Autor
Veejendra K. Yadav
Seitenanzahl
211
Einbandart
Gebundene Ausgabe
Schlagwörter
Steric Effects, Stereoelectronic Effects, Orbital Symmetry and Orbital Overlap Effects, Stereoelectronic Effects on Diastereoselectivity, Stereoelectronic Effects on Reaction Rates
Thema-Inhalt
PNN - Organische Chemie
PNR - Physikalische Chemie
Inhaltsverzeichnis
Steric and Stereoelectronic Control of Organic Molecular Structures and Organic Reactions.- Reactions at Saturated and Unsaturated Carbons.- Diastereoselectivity in Organic Reactions.- A(1,2) and A(1,3) Strains.- The Conservation of Orbital Symmetry (Woodward-Hoffmann Rules).- The Overlap Component of the Stereoelectronic Factor vis-à-vis the Conservation of Orbital Symmetry Rules.- Miscellaneous.
Höhe
235 mm
Breite
15.5 cm
-.-
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