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Bücher Englische Bücher Wissen & Bildung Naturwissenschaft, Medizin, Informatik, Technik Chemie Physikalische Chemie Classical and Quantum Molecular Dynamics in NMR Spectra
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Classical and Quantum Molecular Dynamics in NMR Spectra
Piotr Bernatowicz (Taschenbuch, Englisch)
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Beschreibung
The book provides a detailed account of how condensed-phase molecular dynamics are reflected in the line shapes of NMR spectra. The theories establishing connections between random, time-dependent molecular processes and lineshape effects are exposed in depth. Special emphasis is placed on the theoretical aspects, involving in particular intermolecular processes in solution, and molecular symmetry… issues. The Liouville super-operator formalism is briefly introduced and used wherever it is beneficial for the transparency of presentation. The proposed formal descriptions of the discussed problems are sufficiently detailed to be implemented on a computer. Practical applications of the theory in solid- and liquid-phase studies are illustrated with appropriate experimental examples, exposing the potential of the lineshape method in elucidating molecular dynamics NMR-observable molecular phenomena where quantization of the spatial nuclear degrees of freedom is crucial are addressed in the last part of the book. As an introduction to this exciting research field, selected aspects of the quantum mechanics of isolated systems undergoing rotational tunnelling are reviewed, together with some basic information about quantum systems interacting with their condensed environment. The quantum theory of rate processes evidenced in the NMR lineshapes of molecular rotors is presented, and illustrated with appropriate experimental examples from both solid- and liquid-phase spectra. In this context, the everlasting problem of the quantum-to-classical transition is discussed at a quantitative level. The book will be suitable for graduate students and new and practising researchers using NMR techniques. Dieses Produkt haben wir gerade leider nicht auf Lager.
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Technische Daten
Erscheinungsdatum
20.12.2018
Sprache
Englisch
EAN
9783030080983
Herausgeber
Springer International Publishing
Sonderedition
Nein
Autor
Piotr Bernatowicz
Seitenanzahl
402
Auflage
Softcover reprint of the original 1st edition 2018
Einbandart
Taschenbuch
Schlagwörter
Modelling of NMR Spectroscopy, Vector Model of NMR Experiments, Nuclear Spin Relaxation and NMR Lineshape, Liouville Super-operator Formalism, Quantum Theory of NMR Lineshapes, Molecular Dynamics in Liquids, Hindered Molecular Rotors, Intermolecular Exchange Processes in Liquids, NMR Spectroscopy of Biomolecules
Thema-Inhalt
PNFS - Spektroskopie, Spektrochemie, Massenspektrometrie
PHU - Mathematische Physik
PHFC - Physik der kondensierten Materie (Flüssigkeits- und Festkörperphysik)
Höhe
235 mm
Breite
15.5 cm
Hersteller: Springer Nature Customer Service Center GmbH, Europaplatz 3, Heidelberg, Deutschland, 69115, ProductSafety@springernature.com
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