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Bücher Englische Bücher Wissen & Bildung Naturwissenschaft, Medizin, Informatik, Technik Chemie Anorganische Chemie Nanostructured Metal Oxide Thin Films as Electron Transport Material for Inorganic-Organic Hybrid Perovskite Solar Cells
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Nanostructured Metal Oxide Thin Films as Electron Transport Material for Inorganic-Organic Hybrid Perovskite Solar Cells
Alexander Möllmann (Taschenbuch, Englisch)
Optischer Zustand
Beschreibung
In this work, inorganic-organic hybrid perovskite solar cells were developed and the suitability of binary and ternary metal oxides as electron transport materials in perovskite solar cells was evaluated. Firstly, a standard process for the fabrication of multilayer perovskite solar cell was established, to evaluate the stability and efficiency of above-mentioned metal oxides as ETMs in perovskite… solar cells. Through systematic variation of electron and hole transfer materials, perovskite absorber layers and contact material, PSCs in different configurations were developed. For this purpose, various thin film techniques such as spin coating, spray pyrolysis, atomic layer deposition and plasma enhanced chemical vapor deposition, were used to deposit functional layers in desired architecture. A range of semiconductor metal oxide, such as TiO2, Ta2O5, CeO2, U3O8 and LaNbO4 were tested in this work, because of their optical and electronic properties, wide band gaps and n-type semiconductor behaviour. Compared to prototype ETM TiO2, other compositions, explored in this work, have not been reported in literature as electron transport material in perovskite solar cells and could potentially improve the device efficiency and stability, due to a better band alignment and the lack of photocatalytic activity. The fundamental electron transfer dynamics of the used metal oxides in PSCs were investigated by steady-state and transient photoluminescence spectroscopy. The type of band alignment was determined via ultraviolet photoelectron spectroscopy and Tauc plots. Besides the replacement of the ETM, a superhydrophobic encapsulant, (SiOxCyHz), was deposited by plasma-enhanced chemical vapour deposition, which delayed the degradation of the perovskite absorber as successfully demonstrated by long-term stability studies. Dieses Produkt haben wir gerade leider nicht auf Lager.
Handgeprüfte Gebrauchtware
Bis zu 50 % günstiger als neu
21 Tage Widerrufsrecht
Technische Daten
Erscheinungsdatum
06.02.2020
Sprache
Englisch
EAN
9783843943154
Herausgeber
Dr. Hut
Serien- oder Bandtitel
Anorganische Chemie
Sonderedition
Nein
Autor
Alexander Möllmann
Seitenanzahl
174
Einbandart
Taschenbuch
Schlagwörter
Perovskite, ETM, Metal oxide
Thema-Inhalt
PNK - Anorganische Chemie
Höhe
210 mm
Breite
14.8 cm
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