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Bücher Englische Bücher Wissen & Bildung Naturwissenschaft, Medizin, Informatik, Technik Chemie Physikalische Chemie The Tunnel Effect in Chemistry
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The Tunnel Effect in Chemistry
Ronald Percy Bell (Broschiert, Englisch)
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Beschreibung
The suggestion that quantum-mechanical tunnelling might be a significant factor in some chemical reactions was first made fifty years ago by Hund, very soon after the principles of wave mechanics had been established by de Broglie, Schrodinger and Heisenberg, and similar ideas were put forward during the following thirty years by a number of authors. It was realised from the beginning that such… effects would be particularly prominent in reactions involving the movement of protons or hydrogen atoms, and both theoretical and experimental work received a powerful stimulus in the discovery of deuterium in 1932. During the last twenty years theoretical predictions about the tunnel effect have been supported by an increasing body of experimental evidence, derived especially from studies of hydrogen isotope effects. The present book presents an attempt to summarize this evidence and to indicate the main lines of the basic theory. Details of mathematical manipu lation are restricted mainly to Chapter 2 and the Appendices, and many readers may prefer to confine themselves to the results obtained. The main emphasis has been on the kinetics of chemical reactions involving the transfer of protons, hydrogen atoms or hydride ions, although Chapter 6 gives an account of the role of the tunnel effect in molecular spectra, and Chapter 7 makes some mention of tunnelling in solid state phenomena, biological processes and the electrolytic discharge of hydrogen. Only passing references have been made to tunnelling by electrons. 58,84 €
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Technische Daten
Erscheinungsdatum
01.01.1980
Sprache
Englisch
EAN
9780412213403
Herausgeber
Springer US
Sonderedition
Nein
Autor
Ronald Percy Bell
Seitenanzahl
222
Auflage
1
Einbandart
Broschiert
Schlagwörter
Atom, atoms, biological, chemical reaction, electron, electrons, experiment, hydrogen, hydrogen atom, isotope, kinetics, mechanics, reactions, spectra, wave
Thema-Inhalt
PNR - Physikalische Chemie
Höhe
235 mm
Breite
15.5 cm
Hersteller: Springer Nature Customer Service Center GmbH, ProductSafety@springernature.com
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