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Bücher Englische Bücher Wissen & Bildung Naturwissenschaft, Medizin, Informatik, Technik Chemie Organische Chemie Aromaticity in Heterocyclic Compounds
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Aromaticity in Heterocyclic Compounds
(Broschiert, Englisch)
Optischer Zustand
Beschreibung
Aromaticity is a notion that appeared in the mid-nineteenth century to differentiate between unsaturated hydrocarbons and formally unsaturated benzene [1–3]. At the end of the nineteenth century it seemed that cyclicity was a necessary condition for differentiation between the two, but at the beginning of the twentieth century it turned out that the above assumption was not correct because… cyclooctatetraene exhibited typical properties known for polyenes [4]. The essential property of b- zene-like compounds, often identified with aromatic compounds, was low react- ity. Hence thermodynamic stability was defined as resonance energy [5, 6] and was the first quantitative measure of aromaticity. Many theoretical approaches were proposed later to estimate this quantity, and now the criterion is often considered to be the most fundamental [7]. Almost at the same time, magnetic susceptibility was used to describe aromaticity [8, 9]. Consequently, many concepts based on mag- tism were developed, probably the most effective in assessment of aromaticity being nucleus independent chemical shift (NICS) [10] or Fowler’s maps of ring currents [11]. The criterion served Schleyer as a basis for a definition of aromat- ity: “Compounds which exhibit significantly exalted diamagnetic susceptibility are aromatic. Cyclic delocalisation may also result in bond length equalization, abn- mal chemical shifts and magnetic anisotropies, as well as chemical and physical properties which reflect energetic stabilisation”[12]. 320,99 €
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Technische Daten
Erscheinungsdatum
20.11.2010
Sprache
Englisch
EAN
9783642087936
Herausgeber
Springer Berlin
Serien- oder Bandtitel
Topics in Heterocyclic Chemistry
Sonderedition
Nein
Seitenanzahl
344
Einbandart
Broschiert
Schlagwörter
Aromaticity, heterocyclic chemistry, organic chemistry, resonance energy, tautomer, thermochemistry
Thema-Inhalt
PNN - Organische Chemie
Höhe
235 mm
Breite
15.5 cm
Transparenz & Sicherheit
Hersteller: Springer, Europaplatz 3, Heidelberg, Deutschland, 69115, ProductSafety@springernature.com, Springer Nature Customer Service Center GmbH
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