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Beschreibung
In order to meet the ever-increasing demands for enantiopure compounds, heteroge- ous, homogeneous and enzymatic catalysis evolved independently in the past. Although all three approaches have yielded industrially viable processes, the latter two are the most widely used and can be regarded as complementary in many respects. Despite the progress in structural, computational and mechanistic… studies, however, to date there is no universal recipe for the optimization of catalytic processes. Thus, a trial-and-error approach remains predominant in catalyst discovery and optimization. With the aim of complementing the well-established fields of homogeneous and enzymatic catalysis, organocatalysis and artificial metalloenzymes have enjoyed a recent revival. Artificial metalloenzymes, which are the focus of this book, result from comb- ing an active but unselective organometallic moiety with a macromolecular host. Kaiser and Whitesides suggested the possibility of creating artificial metallo- zymes as long ago as the late 1970s. However, there was a widespread belief that proteins and organometallic catalysts were incompatible with each other. This severely hampered research in this area at the interface between homogeneous and enzymatic catalysis. Since 2000, however, there has been a growing interest in the field of artificial metalloenzymes for enantioselective catalysis. The current state of the art and the potential for future development are p- sented in five well-balanced chapters. G. Roelfes, B. Feringa et al. summarize research relying on DNA as a macromolecular host for enantioselective catalysis. Dieses Produkt haben wir gerade leider nicht auf Lager.
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Technische Daten
Erscheinungsdatum
23.10.2014
Sprache
Englisch
EAN
9783642420672
Herausgeber
Springer Berlin
Serien- oder Bandtitel
Topics in Organometallic Chemistry
Sonderedition
Nein
Seitenanzahl
115
Auflage
1
Einbandart
Broschiert
Bandzählung
25
Schlagwörter
Bio-inspired Catalysis, DNA, DNA based Catalysis, Hybrid Catalyst, Metalloenzymes, Metalloproteins, Organometallic Chemistry, Oxidation, catalysis, proteins
Thema-Inhalt
PNND - Metallorganische Chemie
PNRD - Katalyse
PSB - Biochemie
PNK - Anorganische Chemie
PNB - Medizinische Chemie, Pharmazeutische Chemie
Höhe
235 mm
Breite
15.5 cm
Hersteller: Springer Nature Customer Service Center GmbH, Europaplatz 3, Heidelberg, Deutschland, 69115, ProductSafety@springernature.com
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