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Bücher Englische Bücher Wissen & Bildung Naturwissenschaft, Medizin, Informatik, Technik Chemie Organische Chemie Chemically Induced Dynamic Nuclear and Electron Polarizations-CIDNP and CIDEP
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Chemically Induced Dynamic Nuclear and Electron Polarizations-CIDNP and CIDEP
C. Richard, P. Granger (Broschiert, Englisch)
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Beschreibung
Anomalous electron-spin state populations in the Electron Paramagnetic Re sonance (EPR) spectra of radicals formed during radio lysis experiments were observed in 1963 by FESSENDEN and SCHULER [170a]. This phenomenon did not receive much attention at the time. In 1967, BARGON, FISCHER, and JOHNSEN [5] and independently WARD and LAWLER [7,8] reported a similar phenomenon for Nuclear Magnetic… Resonance (NMR) spectra taken during radical reactions: emission or enhanced absorption, or both. The earliest attempts to explain this new NMR phenomenon treated these effects in a way similar to that of Dynamic Nuclear Polarization (DNP) or the Overhauser effect. Although the polarization has a completely different origin, DNP gave its name to this effect: Chemically Induced Dynamic Nuclear Polariza tion (CIDNP). [The name Chemically Induced Dynamic Electron Polarization (CIDEP) was introduced later by analogy with CIDNP]. After the initial publica tions, all the new data demonstrated that the first theory could not be correct. In 1969, a new theory was proposed by CLOSS [18] and independently by KAPTEIN and OOSTERHOFF [23] and called the radical-pair theory. This mechanism was proposed to account for the observations of polarization in both NMR and EPR. The radical-pair theory is based on weak interactions in a pair of radicals: the strength of interaction between the electronic states of the radicals depends in particular on the nuclear-spin states. Dieses Produkt haben wir gerade leider nicht auf Lager.
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Technische Daten
Erscheinungsdatum
15.11.2011
Sprache
Englisch
EAN
9783642657955
Herausgeber
Springer Berlin
Serien- oder Bandtitel
NMR Basic Principles and Progress
Sonderedition
Nein
Autor
C. Richard, P. Granger
Seitenanzahl
130
Auflage
1
Einbandart
Broschiert
Hersteller: Springer Nature Customer Service Center GmbH, Europaplatz 3, Heidelberg, Deutschland, 69115, ProductSafety@springernature.com
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