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Bücher Englische Bücher Wissen & Bildung Naturwissenschaft, Medizin, Informatik, Technik Physik & Astronomie Atomphysik & Kernphysik Optical Studies in Liquids and Solids
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Optical Studies in Liquids and Solids
(Broschiert, Englisch)
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Beschreibung
The study of the vibrations of polyatomic molecules has recently turned into one of the most widespread and powerful methods of studying molecular structure. These vibrations ap pear directly in the infrared absorption spectra and Raman spectra of gases, liquids, and solids. A measurement of the number of bands in addition to their positions (frequencies or wavelengths) offers the possibility of… obtaining a great deal of important information regarding the geometric and mechanical properties of the molecules, the types of chemical bonds, and so forth. It is now quite difficult to list the vast number of specific problems solved by measuring vibrational fre quencies. As a result of the successful development of research methods and the widespread applica tion of vibrational spectra in analyzing the structures of molecules and the constitution of ma terials, it now becomes necessary to develop the theory of molecular vibrations further. Existing theory, of course, is based on the assumption of the harmonicity of molecular vi brations, which, strictly speaking, is not justified experimentally. The anharmonicity of the molecular vibrations has therefore to be taken into account by introducing appropriate approxi mations. Thus, in carrying out calculations on the vibrations of polyatomic molecules, one uses the force constants calculated from the observed frequency values. However, as a result of the anharmonicity of the vibrations, the values of the observed frequencies differ from the harmonic values, and the force constants used therefore differ from the true ones, i. e. 53,49 €
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Technische Daten
Erscheinungsdatum
10.01.2014
Sprache
Englisch
EAN
9781468487268
Herausgeber
Springer US
Serien- oder Bandtitel
The Lebedev Physics Institute Series
Sonderedition
Nein
Seitenanzahl
266
Einbandart
Broschiert
Schlagwörter
Vibration, chemical bond, collision, development, experiment, information, mechanical property, molecule, scattering, sorption, spectra, structure
Thema-Inhalt
PHM - Atom- und Molekularphysik
Höhe
279 mm
Breite
21 cm
Transparenz & Sicherheit
Hersteller: Springer Nature Customer Service Center GmbH, Europaplatz 3, Heidelberg, Deutschland, 69115, ProductSafety@springernature.com
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