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Bücher Englische Bücher Wissen & Bildung Naturwissenschaft, Medizin, Informatik, Technik Chemie Synthesis of Chiral Rare Earth and Alkaline Earth Compounds
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Synthesis of Chiral Rare Earth and Alkaline Earth Compounds
Meng He (Broschiert, Englisch)
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Beschreibung
The first chiral amidinate borohydride rare earth compounds and compounds based on (S)-HPEBA ((S,S)-N,N-bis-(1-phenylethyl)benzamidine) ligand were reported by Roesky et al. To continuing this work, the new chiral ligand (S)-HNEBA ((S,S)-N,N-bis-(1-naphthylethyl)benzamidine) were synthesized. The corresponding amidinate metal complexes were successfully obtained by amine elimination. The… luminescent and magnetic properties of rare earth compounds were studied.
Alkaline earth metal compounds have been extensively studied as catalysts in synthetic chemistry. However, chiral amidinate alkaline earth metal complexes have never been reported. Chiral amidinate ligand (S)-HPEBA was introduced into the coordination chemistry of the alkaline earth metal as well as divalent lanthanides, their catalytic activities in hydrophosphination have been investigated. The Ba compound showed high catalytic activities in the hydrophosphination reaction.
Moreover, since rare earth metal COT complexes exhibit excellent SMM behavior, it is of great interest to study the magnetic behavior of COT amidinate complexes. Thus, amidine ligand (S)-HPEBA and (S)-HPETA are introduced into the corresponding COT amidinate complexes for magnetic properties studies. The Er Compound exhibited typical field-induced SMM behavior. Furthermore, inspired by the promising application of lanthanide SMMs and the research of SMMs based on sandwich type lanthanide complexes, a series of novel sandwich type complexes comprising of Pc and COT ligand were designed and synthesized. 33,65 €
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Technische Daten
Erscheinungsdatum
16.08.2016
Sprache
Englisch
EAN
9783736993303
Herausgeber
Cuvillier Verlag
Sonderedition
Nein
Autor
Meng He
Seitenanzahl
134
Auflage
1
Einbandart
Broschiert
Buch Untertitel
Magnetism and Catalytic Studies
Schlagwörter
chemistry, lanthanide, catalysis, magnetism
Thema-Inhalt
PNK - Anorganische Chemie
Höhe
2100 mm
Breite
148 cm
Hersteller: Cuvillier, Nonnenstieg 8, Göttingen, Deutschland, 37075, info@cuvillier.de, info@cuvillier.de
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