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- Startseite
Bücher Wissen & Bildung Englische Bücher Naturwissenschaft, Medizin, Informatik, Technik Physik & Astronomie Thermodynamik Efficient Control and Spontaneous Transitions
Derzeit nicht verfügbar
Handgeprüfte Gebrauchtware
Bis zu 50 % günstiger als neu
21 Tage Widerrufsrecht
Optischer Zustand
Beschreibung
This thesis addresses deep questions that cut to the physical and informational essence of central chemical quantities such as transition paths and reaction mechanisms and proposes fundamental new connections between transition-path theory, linear-response theory, nonequilibrium thermodynamics, and information theory. The author investigates slow, energetically efficient driving protocols that… drive a system between conformations corresponding to endpoints of a reaction, aiming to find connections between principles of efficient driving and the spontaneous transition mechanism in the absence of driving. First, an alternative perspective of transition-path theory is developed that unifies it with stochastic thermodynamics to describe flows of entropy, energy, and information during the reaction. This also provides an optimization criterion for selecting collective variables. Next, protocols are designed which invert the magnetization of a 3×3 Ising model with minimal energetic cost,and it is determined that using multiple control parameters allows the system to be driven along a fast-relaxing pathway between reaction endpoints. Finally, the author compares these protocols with the spontaneous transition mechanism for magnetization inversion in the same Ising model, finding that designed protocols capture general features of the spontaneous mechanism and energetics given the constraints on the control parameters. This work represents a major step forward in our understanding of rare events and provides a basis for investigating the connection between efficient protocols and spontaneous transition mechanisms which can be further probed in a wider variety of systems. Dieses Produkt haben wir gerade leider nicht auf Lager.
Handgeprüfte Gebrauchtware
Bis zu 50 % günstiger als neu
21 Tage Widerrufsrecht
Technische Daten
Erscheinungsdatum
27.10.2023
Sprache
Englisch
EAN
9783031405334
Herausgeber
Springer International Publishing
Serien- oder Bandtitel
Springer Theses
Sonderedition
Nein
Autor
Miranda Louwerse
Seitenanzahl
113
Einbandart
Gebundene Ausgabe
Autorenporträt
Dr. Miranda Louwerse obtained a Bachelor of Science in Chemistry and Mathematics from the University of the Fraser Valley in 2017 before beginning a PhD in Chemistry at Simon Fraser University. She joined Dr. David Sivak’s research group in the physics department and carried out interdisciplinary research at the intersection of chemistry, physics, biology, and statistics. Upon completing her PhD in 2022, Miranda found employment as a data scientist in the biotech industry. Miranda has been married to her husband Mitch since 2018 and spends her time fishing with him and her two-year old border collie Roscoe.
Schlagwörter
Reaction mechanisms, stochastic dynamics, transition-path theory, minimum-work protocols, information thermodynamics, nonequilibrium thermodynamics, minimum work control theory
Thema-Inhalt
PHH - Thermodynamik und Wärme
PHVN - Biophysik
PSB - Biochemie
PNRP - Quanten- und theoretische Chemie
GPJ - Kodierungstheorie und Verschlüsselung (Kryptologie)
GPF - Informationstheorie
PHFC - Physik der kondensierten Materie (Flüssigkeits- und Festkörperphysik)
Höhe
235 mm
Breite
15.5 cm
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Transparenz & Sicherheit
Hersteller: Springer, Europaplatz 3, Heidelberg, Deutschland, 69115, ProductSafety@springernature.com, Springer Nature Customer Service Center GmbH
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