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Bücher Englische Bücher Wissen & Bildung Naturwissenschaft, Medizin, Informatik, Technik Chemie Anorganische Chemie (Electro)chemical Activation of Dinitrogen with Transition Metal Complexes and Electrochemical and Optical Properties of Redox-Active Heteroatom-Functionalized Polyacetylenes
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(Electro)chemical Activation of Dinitrogen with Transition Metal Complexes and Electrochemical and Optical Properties of Redox-Active Heteroatom-Functionalized Polyacetylenes
Nils Ostermann (Unbekannter Einband, Englisch)
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Optischer Zustand
Beschreibung
Electron transfer reactions are key steps in chemical transformations. Commonly proceeded by the use of chemical oxidizing and reducing agents, the use of the electrochemistry offers a promising alternative. The simple tunability of the redox potential at the electrode and the production of less chemical waste outline the advantages of the electrochemistry over chemical redox agents. Furthermore,… in the context of going to renewable energy resources, the use of green energy like sunlight or wind can be used as the energy input. Following this more sustainable approach of electrosynthesis, researchers developed growing interest in the field of molecular electrochemistry during the last decades.
The use of electrochemistry not only offers a greener alternative to common synthetic approaches, but also provides a powerful tool to understand electron transfer reactions. With the use of cyclic voltammetry (CV), exact redox potentials can be defined and thermodynamic and kinetic information of the electron transfer and follow up reactions as well as catalytic efficiencies can be investigated. However, electrochemistry does not provide insights about structural information of intermediates or products. Hence, spectroelectrochemical (SEC) techniques were developed to combine the advantages of electrochemistry with molecular spectroscopy to further understand reaction mechanisms. Upon potential control spectroscopic profiles can be in situ generated including spectra of vibrational frequencies, molar absorptivities, luminescence intensities and electronic or magnetic resonance frequencies.
The ability to understand chemical and electrochemical processes will be examined in this thesis for different molecular systems. Insights into electronic properties could be gained with the help of electrochemical measurements. In this context, cyclic voltammetry studies and controlled potential electrolysis (CPE) as well as combined spectroelectrochemical experiments, in particular UV/Vis/nIR/IR-SEC measurements were performed. Dieses Produkt haben wir gerade leider nicht auf Lager.
Handgeprüfte Gebrauchtware
Bis zu 50 % günstiger als neu
Der Umwelt zuliebe
Technische Daten
Erscheinungsdatum
22.11.2023
Sprache
Englisch
EAN
9783967292237
Herausgeber
Mensch & Buch
Sonderedition
Nein
Autor
Nils Ostermann
Seitenanzahl
200
Auflage
1
Einbandart
Unbekannter Einband
Einbandart Details
Klebebindung
-.-
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